MARTINA MOLINARI

PhD Graduate

PhD program:: XXXVII


supervisor: Dr. Matteo D'Onorio
co-supervisor: Prof. Gianfranco Caruso

Thesis title: Activated Corrosion Products: Experimental and Numerical Investigations for Tokamak-Type Fusion Plants Applications

In the context of advancing in nuclear fusion technology, ensuring the safety of a Fusion Power Plant (FPP) is crucial because of the inherent complexities of fusion reactions and the challenges posed by the demanding operational conditions. Nuclear fusion technology is still under development, and therefore, it is essential to adopt approaches, techniques, and strategies to address and overcome the technical and scientific challenges hindering progress toward a functional and safe fusion plant. The ultimate goal is to create a complex and integrated system capable of achieving the safety objective, which is to ensure that a nuclear facility does not pose a significant risk to people and the environment. This thesis investigates both experimentally and numerically the behavior of contaminants into a cooling loops since those contaminant affect Occupational Radiation Exposure (ORE) and the waste managment and disposal. A portion of the mentioned contaminants in water loops of tokamak-type FPP, consists of Activated Corrosion Products (ACP). The study includes experimental investigations of materials selected for the European DEMOnstrator (EU-DEMO) project, as well as numerical analyses for both the EU-DEMO and Divertor Tokamak Test (DTT) projects, with the goal of supporting the safety design of selected components. Additionally, a physical model was developed to enhance the theoretical tools available, with the long-term objective of providing more reliable and realistic safety analyses. This dissertation has two separated parts dedicated to: experimental investigation and numerical analyses and modeling. During the experimental investigation a test apparatus has been used to study the corrosion behaviour of iron based alloys in DEMO-like environemts. A water solution has been used as working fluid, with variation in alkali concentration and dissolved oxygen concentration into the solution. Part two is dedicated to numerical analyses and modeling. With the OSCAR-Fusion code the effect of water chemistry on ACP buildup has been assessed for the PHTS of the DEMO Plasma Facing Unit, (PFU) and the Water Cooling System (WCS) of the DTT Vacuum Vessel (VV) support safety-oriented design. The analyses conducted for the DEMO PFU were based on the oscar-Fusion V1.3 code, with two key parameters being perturbed: the lithium hydroxide concentration in the coolant and the standardized corrosion rate coefficients. Differently, the DTT analyses were focused on the data set development from scratch using available data and assumptions. The assessment have been done with two different configuration of the purification system (i.e., Chemical Volume Control System (CVCS)) to compare the effects of the two configurations on the distribution of activities in the circuit and the surface activities of the components. The modeling section of the second part of this dissertation, deals with one of the theoretical tools limitation: the effect of magnetic field on ACP behaviour has never been explored yet. To address this, a physical model was developed to improve the OSCAR-Fusion code ability to simulate how ACP transport and deposition may be affected by the magnetic field. The magnetophoresis phenomenon was incorporated into the model, with new mass transfer coefficients defined to account for magnetic field effects, and a new correlation for the deposition phase. Preliminary experimental investigations have recently confirmed the outcomes. This study contributes to the understanding of corrosion processes in FPP, offering insights that are essential for refining safety and design considerations. This has been done by systematically investigating the corrosion mechanisms that occur under the extreme conditions typical of fusion environments—such as high radiation flux, elevated temperatures, and the presence of reactive Plasma Facing Components (PFC). The findings are useful for informing the design and operational frameworks necessary to enhance the structural integrity and longevity of FPP. Furthermore, this work lays the foundation for future studies aimed at addressing corrosion-related challenges and more reliable safety analyses, ultimately supporting the progression toward the commercialization of fusion energy by improving the reliability and safety of FPP over their operational lifespan.

Research products

11573/1714160 - 2024 - Nuclear safety Enhanced: A Deep dive into current and future RAVEN applications
D'onorio, Matteo; Glingler, Tommaso; Molinari, Martina; Maccari, Pietro; Mascari, Fulvio; Mandelli, Diego; Alfonsi, Andrea; Caruso, Gianfranco - 01a Articolo in rivista
paper: NUCLEAR ENGINEERING AND DESIGN (Elsevier BV:PO Box 211, 1000 AE Amsterdam Netherlands:011 31 20 4853757, 011 31 20 4853642, 011 31 20 4853641, EMAIL: nlinfo-f@elsevier.nl, INTERNET: http://www.elsevier.nl, Fax: 011 31 20 4853598) pp. 1-17 - issn: 0029-5493 - wos: WOS:001262413100001 (2) - scopus: 2-s2.0-85196955576 (2)

11573/1723795 - 2024 - Experimental insights on iron-based alloys corrosion in water cooled loops
Molinari, Martina; Lo Piccolo, Eugenio; Torella, Raffaele; D'onorio, Matteo; Terranova, Nicholas; Caruso, Gianfranco - 01a Articolo in rivista
paper: NUCLEAR MATERIALS AND ENERGY (Oxford: Elsevier Ltd.) pp. 1-10 - issn: 2352-1791 - wos: WOS:001346162200001 (0) - scopus: (0)

11573/1683688 - 2023 - Water chemistry impact on activated corrosion products. An assessment on tokamak reactors
Molinari, Martina; D'onorio, Matteo; Mariano, Giovanni; Terranova, Nicholas; Caruso, Gianfranco - 01a Articolo in rivista
paper: ENERGIES (Basel : Molecular Diversity Preservation International) pp. 1-15 - issn: 1996-1073 - wos: WOS:001016983200001 (2) - scopus: 2-s2.0-85163864662 (2)

11573/1681356 - 2023 - Transient analysis of SIRIO using RELAP5/MOD3.3 system code
Molinari, Martina; Narcisi, Vincenzo; Caramello, Marco; Tarantino, Mariano; Giannetti, Fabio - 04c Atto di convegno in rivista
paper: JOURNAL OF PHYSICS. CONFERENCE SERIES (Bristol : Institute of Physics Publishing) pp. 1-11 - issn: 1742-6588 - wos: (0) - scopus: 2-s2.0-85163546357 (0)
conference: 39th UIT Heat Transfer International Conference 2022, UIT 2022 (Gaeta, Italy)

11573/1657087 - 2022 - RAVEN/OSCAR-Fusion coupling for activated corrosion products assessments, sensitivity, and uncertainty quantification
D'onorio, M.; Molinari, M.; Mariano, G.; Terranova, N. - 01a Articolo in rivista
paper: IEEE TRANSACTIONS ON PLASMA SCIENCE (IEEE / Institute of Electrical and Electronics Engineers Incorporated:445 Hoes Lane:Piscataway, NJ 08854:(800)701-4333, (732)981-0060, EMAIL: subscription-service@ieee.org, INTERNET: http://www.ieee.org, Fax: (732)981-9667) pp. 1-8 - issn: 0093-3813 - wos: WOS:000829201300001 (4) - scopus: 2-s2.0-85135221593 (4)

11573/1645686 - 2022 - Transient analysis of OSU-MASLWR with RELAP5
Molinari, M.; Narcisi, V.; Ciurluini, C.; Giannetti, F. - 04c Atto di convegno in rivista
paper: JOURNAL OF PHYSICS. CONFERENCE SERIES (Bristol : Institute of Physics Publishing) pp. 1-9 - issn: 1742-6588 - wos: (0) - scopus: 2-s2.0-85128866773 (4)
conference: 38th UIT Heat Transfer International Conference 2021, UIT 2021 (Gaeta (LT), Italy (Online))

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