ANACLETO PROIETTI

Dottore di ricerca

ciclo: XXXVII


supervisore: Prof. Marco Rossi

Titolo della tesi: Advanced Characterisation and Failure Analysis of GaN HEMT Devices and Related Technologies | Optimization of Critical Technology Processes for High Performance and High Reliability GaN HEMT Devices (GaNAPA project)

Gallium Nitride (GaN) High Electron Mobility Transistors (HEMT) are among the most promising technologies for high frequency and high power applications due to their excellent switching properties thanks to the formation of a two dimensional electron gas (2DEG). However, their integration into complex systems still faces critical challenges in terms of fabrication defects and reliability. This thesis presents an extensive study on the failure mechanisms and on the fabrication related issues of GaN HEMT devices (chapter 1), with a particular focus on real case scenario and advanced characterisation techniques of the full in-line process (chapter 2). The first part of the experimental work (chapter 3) is dedicated to failure analysis of packaged GaN devices integrated in antenna modules. A dedicated analysis protocol was developed to identify the failure origin and distinguish between first and second-generation device designs. The methodology revealed a dramatic reduction in failure rates from approximately 35% to below 10% within single wafers, proving the effectiveness of design and process improvements in mitigating failure mechanisms. A second failure scenario is explored in depth, involving void formation beneath the central via hole of QFN packaged devices. A thermo-mechanical hypothesis is proposed: trapped air during resin curing expands upon heating, forming internal voids that compromise thermal dissipation. This leads to a self-reinforcing degradation process ultimately responsible for catastrophic device failure. Complementing these case studies, the thesis investigates the correlation between growth conditions, defect morphology, and electrical properties on the starting substrate (chapter 4). Advanced microscopic and spectroscopic techniques, including Conductive Atomic Force Microscopy, Raman spectroscopy, Scanning and Transmission Electron Microscopy, were employed to characterize the typical crystal defects such as hexagonal and triangular holes (namely V-pits), growth hillocks, and dislocation related features. Overall, this work underscores the necessity of combining failure analysis protocols with nanoscale material characterisation to improve the reliability and scalability of GaN based electronic devices.

Produzione scientifica

11573/1744399 - 2025 - Multidisciplinary characterization of fungi and cyanobacteria involved in biodeterioration of the Tomba delle Leonesse, Tarquinia, Italy
Kratter, Matilde; Beccaccioli, Marzia; Benedetti, Francesca; Buccini, Luca; Proietti, Anacleto; Zanellato, Gianluca; Tomassetti, Maria Cristina; Rossi, Marco; Faino, Luigi; Reverberi, Massimo; Bathany, Katell; Tokarski, Caroline; Battistuzzi, Mariano; Boccia, Beatrice; La Rocca, Nicoletta; Rinaldi, Teresa - 01a Articolo in rivista
rivista: INTERNATIONAL BIODETERIORATION & BIODEGRADATION (Elsevier Applied Science:An Imprint of Elsevier Science Ltd, The Boulevard, Langford Lane, Kidlington Oxford OX5 1GB United Kingdom:011 44 1865 843000, 011 44 1865 843699, EMAIL: nlinfo-f@elsevier.nl OR usinfo-f@elsevier.com OR forinfo-kyf04035@niftyserve.or.jp, INTERNET: http://www.elsevier.nl/, Fax: 011 44 1865 843010) pp. - - issn: 0964-8305 - wos: (0) - scopus: 2-s2.0-105013097319 (0)

11573/1733831 - 2025 - High-Resolution and Surface-Sensitive Tip-Enhanced Raman Spectroscopy Characterization of Strained-Silicon Devices through Cleanroom-Compatible Plasmonic Probes
Mancini, Chiara.; Proietti, Anacleto.; La Penna, Giancarlo.; Buccini, Luca.; Passeri, Daniele.; Gambacorti, Narciso.; Rossi, Marco. - 01a Articolo in rivista
rivista: ADVANCED MATERIALS INTERFACES (WILEY-VCH Verlag GmbH & Co) pp. - - issn: 2196-7350 - wos: WOS:001416321000001 (0) - scopus: 2-s2.0-85217200117 (0)

11573/1740092 - 2025 - Analytical methods for nanomaterials investigation in food and food-related materials
Passeri, Daniele; Atanasio, Pierfrancesco; Proietti, Anacleto; Mancini, Chiara; Cognigni, Flavio; La Penna, Giancarlo; Buccini, Luca; Rossi, Marco; Turco Anna, Chiara; D'amato, Marilena; Sorbo, Aorbo; Dinarelli, Simone; D'ettorre, Giulia; Aureli, Federica - 01a Articolo in rivista
rivista: APPLIED FOOD RESEARCH (Amsterdam: Elsevier B.V) pp. - - issn: 2772-5022 - wos: WOS:001424090800001 (0) - scopus: 2-s2.0-85216711564 (0)

11573/1739710 - 2025 - Non‐invasive analyses of an etruscan fibula from Vulci (Italy). The benefits of a combination of Micro‐Raman spectroscopy, 3D reconstruction through X‐Ray microscopy and ED‐XRF with Monte Carlo simulation
Porcaro, Marta; Cognigni, Flavio; Bernabale, Martina; La Penna, Giancarlo; Proietti, Anacleto; Carlo, Casi; Regoli, Carlo; Carosi, Simona; Rossi, Marco; Brunetti, Antonio; De Vito, Caterina - 01a Articolo in rivista
rivista: JOURNAL OF RAMAN SPECTROSCOPY (John Wiley & Sons Limited:1 Oldlands Way, Bognor Regis, P022 9SA United Kingdom:011 44 1243 779777, EMAIL: cs-journals@wiley.co.uk, INTERNET: http://www.wiley.co.uk, Fax: 011 44 1243 843232) pp. 1-13 - issn: 0377-0486 - wos: (0) - scopus: (0)

11573/1738805 - 2025 - Multiscale characterization of laser-induced defects in the production of heterojunction photovoltaic cells
Proietti, Anacleto; Buccini, Luca; Atanasio, Pierfrancesco; Mancini, Chiara; La Penna, Giancarlo; Di Conzo, Corrado; Mura, Francesco; Khan, Wajahat; Galiazzo, Marco; Frasson, Nicola; Querci, Alessandra; Passeri, Daniele; Rossi, Marco - 01a Articolo in rivista
rivista: MATERIALS TODAY PHYSICS ([Oxford]: Elsevier Ltd.) pp. - - issn: 2542-5293 - wos: (0) - scopus: 2-s2.0-86000621997 (0)

11573/1730490 - 2024 - Graphene Quantum Dots from Agricultural Wastes: Green Synthesis and Advanced Applications for Energy Storage
Atanasio, Pierfrancesco; Zampiva, Rubia Y. S.; Buccini, Luca; Di Conzo, Corrado; Proietti, Anacleto; Mura, Francesco; Aurora, Annalisa; Marrani, Andrea G.; Passeri, Daniele; Rossi, Marco; Pasquali, Mauro; Scaramuzzo, Francesca A. - 01a Articolo in rivista
rivista: MOLECULES (Basel: MDPI Berlin: Springer, 1996-) pp. 1-19 - issn: 1420-3049 - wos: WOS:001376417500001 (4) - scopus: 2-s2.0-85211903284 (5)

11573/1718932 - 2024 - Combined use of 3D X-ray microscopy and correlative microscopy for chemical-physical investigation of bronze Phoenician coins
Bernabale, M.; Cognigni, F.; Contessi, S.; Proietti, A.; Mancini, C.; Spagnoli, F.; De Vito, C.; Rossi, Marco - 04d Abstract in atti di convegno
congresso: 110° Congresso Nazionale SIF (Bologna)
libro: 110° Congresso Nazionale SIF - (9788874381401)

11573/1723152 - 2024 - Correlative analysis of advanced microscopy techniques for metallography and corrosion microstructures of bronze phoenician coins
Bernabale, Martina; Cognigni, Flavio; Contessi, Silvia; Proietti, Anacleto; Mancini, Chiara; Spagnoli, Federica; Rossi, Marco; De Vito, Caterina - 01a Articolo in rivista
rivista: MATERIALS CHARACTERIZATION (Elsevier Science Incorporated / NY Journals:Madison Square Station, PO Box 882:New York, NY 10159:(212)633-3730, EMAIL: usinfo-f@elsevier.com, INTERNET: http://www.elsevier.com, Fax: (212)633-3680) pp. - - issn: 1044-5803 - wos: (0) - scopus: 2-s2.0-85206181741 (2)

11573/1718094 - 2024 - Biorestoration Potential of Carbonatogenic Bacteria on Lithotypes: SEM and AFM characterization
Buccini, Luca; Benedetti, Francesca; Kratter, Matilde; Mura, Francesco; Proietti, Anacleto; Atanasio, Pierfrancesco; Cirigliano, Angela; Rossi, Marco; Rinaldi, Teresa; Passeri, Daniele - 04f Poster
congresso: European Microscopy Congress 2024 (Copenaghen)
libro: EMC 2024 Abstract Book - ()

11573/1713453 - 2024 - From AFM to TERS: Unveiling the Nanoscale Morphological and Chemical Composition of Bovine Milk-Derived Extracellular Vesicles
Buccini, Luca; Proietti, Anacleto; La Penna, Giancarlo; Mancini, Chiara; Mura, Francesco; Rossi, Marco; Passeri, Daniele - 04f Poster
congresso: Symposium on microscopic characterization of the solid/liquid interface (Vallesana training center, Sondalo (Sondrio, Lombardia, Italia))
libro: Symposium on microscopic characterization of the solid/liquid interface - ()

11573/1718093 - 2024 - Raman and Tip-Enhanced Raman spectroscopy characterization of milk-derived extracellular vesicles: Toward nanoscale single vesicle analysis
Buccini, Luca; Proietti, Anacleto; La Penna, Giancarlo; Mancini, Chiara; Mura, Francesco; Rossi, Marco; Passeri, Daniele - 04f Poster
congresso: 28th International Conference on Raman Spectroscopy – ICORS 2024 (Rome)
libro: ICORS-2024 - ()

11573/1709439 - 2024 - Toward the nanoscale chemical and physical probing of milk-derived extracellular vesicles using Raman and tip-enhanced Raman spectroscopy
Buccini, Luca; Proietti, Anacleto; La Penna, Giancarlo; Mancini, Chiara; Mura, Francesco; Tacconi, Stefano; Dini, Luciana; Rossi, Marco; Passeri, Daniele - 01a Articolo in rivista
rivista: NANOSCALE (Cambridge,UK: RCS PUBLISHING -Royal Society of Chemistry) pp. 8132-8142 - issn: 2040-3364 - wos: WOS:001196109900001 (8) - scopus: 2-s2.0-85189558073 (7)

11573/1724131 - 2024 - Long-term monitoring of the hypogeal Etruscan Tomba degli Scudi, Tarquinia, Italy. Early detection of black spots, investigation of fungal community, and evaluation of their biodeterioration potential
Kratter, Matilde; Beccaccioli, Marzia; Vassallo, Ylenia; Benedetti, Francesca; La&Nbsp;, ; La Penna, Giancarlo; Proietti, Anacleto; Zanellato, Gianluca; Faino, Luigi; Cirigliano, Angela; Neisje&Nbsp;, De&Nbsp;; Kruif, Fiona; Tomassetti Maria, Cristina; Rossi, Marco; Reverberi, Massimo; Quagliariello, Andrea; Rinaldi, Teresa - 01a Articolo in rivista
rivista: JOURNAL OF APPLIED MICROBIOLOGY (Oxford: Blackwell Science.) pp. - - issn: 1365-2672 - wos: (0) - scopus: 2-s2.0-85207601454 (3)

11573/1709435 - 2024 - Strained silicon technology: non-destructive high-lateral-resolution characterization through tip-enhanced raman spectroscopy
La Penna, Giancarlo; Mancini, Chiara; Proietti, Anacleto; Buccini, Luca; Passeri, Daniele; Gambacorti, Narciso; Richy, Jérôme; Rossi, Marco - 01a Articolo in rivista
rivista: APPLIED SPECTROSCOPY (- [London]: SAGE - [Frederick Md.]: Society for Applied Spectroscopy) pp. - - issn: 1943-3530 - wos: WOS:001204877400001 (3) - scopus: 2-s2.0-85190769815 (3)

11573/1702058 - 2024 - Carbon nanodots from orange peel waste as fluorescent probes for detecting nitrobenzene
Michenzi, Cinzia; Proietti, Anacleto; Rossi, Marco; Espro, Claudia; Bressi, Viviana; Vetica, Fabrizio; Simonis, Beatrice; Chiarotto, Isabella - 01a Articolo in rivista
rivista: RSC SUSTAINABILITY (Cambridge: Royal Society of Chemistry, 2023-) pp. 1-10 - issn: 2753-8125 - wos: WOS:001266007900001 (17) - scopus: 2-s2.0-85184937387 (17)

11573/1724748 - 2024 - Analyzing the structure and chemical composition of an Etruscan bronze fibula from Tomb Number 129 at Vulci (VT, Italy) through a non-destructive multi-analytical approach
Porcaro, M.; Cognigni, F.; La Penna, G.; Proietti, A.; Regoli, Carlo.; Casi, Carlo.; Carosi, S.; Rossi, Marco; Brunetti, Antonio.; De Vito, C. - 04d Abstract in atti di convegno
congresso: Congresso congiunto SGI-SIMP (Bari)
libro: Geology for a sustainable management of our Planet - ()

11573/1719593 - 2024 - Multi-scale Characterization of laser-induced defects in the production of heterojunction photovoltaic cells
Proietti, Anacleto; Buccini, Luca; Atanasio, Pierfrancesco; La Penna, Giancarlo; Mancini, Chiara; Di Conzo, Corrado; Mura, Francesco; Galiazzo, Marco; Frasson, Nicola; Passeri, Daniele; Rossi, Marco - 04f Poster
congresso: European Microscopy Congress 2024 (EMC 2024) (Copenaghen)
libro: EMC 2024 - ()

11573/1701832 - 2024 - Strained silicon Technology: Non-destructive nanoscale characterization through Tip-Enhanced Raman Spectroscopy
Proietti, Anacleto; Mancini, Chiara; La Penna, Giancarlo; Atanasio, Pierfrancesco; Buccini, Luca; Passeri, Daniele; Rossi, Marco - 04f Poster
congresso: WORKSHOP SHARESCIENCE (Rome, Italy)
libro: WORKSHOP SHARESCIENCE - ()

11573/1691309 - 2023 - Analysis of Roman Era archaeological finds from Museo Territoriale del Lago di Bolsena with non-destructive investigation techniques
Alemanno, Valentina; Atanasio, Pierfrancesco; La Penna, Giancarlo; Mancini, Chiara; Cognigni, Flavio; Silvestri, Serena; Proietti, Anacleto; Rossi, Marco; Ciccola, Alessandro; Nucara, Alessandro; Barbaro, Barbara; Binaco, Paolo; Dini, Danilo - 04b Atto di convegno in volume
congresso: MetroArchaeo - 2023 IMEKO INTERNATIONAL CONFERENCE ON Metrology for Archaeology and Cultural Heritage (Roma)
libro: 2023 IMEKO International conference on metrology for archaelogy and cultural heritage. Metro archaeo - (9789299009062)

11573/1700497 - 2023 - Analysis of Roman era archaeological finds from Museo Territoriale del Lago di Bolsena with non-destructive investigation techniques
Alemanno, Valentina; Atanasio, Pierfrancesco; La Penna, Giancarlo; Mancini, Chiara; Cognigni, Flavio; Silvestri, Serena; Proietti, Anacleto; Rossi, Marco; Ciccola, Alessandro; Nucara, Alessandro; Barbaro, Barbara; Binaco, Paolo; Dini, Danilo - 04b Atto di convegno in volume
congresso: International Conference on Metrology for Archaeology and Cultural Heritage (Rome, Italy)
libro: Proceedings - IMEKO TC4 International Conference on Metrology for Archaeology and Cultural Heritage - (978-92-990090-6-2)

11573/1689258 - 2023 - Rice Husk Waste-Derived Carbon Aerogels: A Sustainable Approach for Advanced Supercapacitor Electrodes
Atanasio, Pierfrancesco; Scaramuzzo, Francesca Anna; Proietti, Anacleto; Pasquali, Mauro; Rossi, Marco - 04f Poster
congresso: Nanoinnovation 2023 (Rome, Italy)
libro: Nanoinnovation 2023: Poster session - ()

11573/1684356 - 2023 - 3D fractures analysis and conservation assessment of wrought iron javelin through advanced non-invasive techniques
Bernabale, Martina; Cognigni, Flavio; Mancini, Chiara; Proietti, Anacleto; Mura, Francesco; Montanari, Daria; Nigro, Lorenzo; Rossi, Marco; De Vito, Caterina - 01a Articolo in rivista
rivista: SCIENTIFIC REPORTS (London: Springer Nature London: Nature Publishing Group) pp. 1-11 - issn: 2045-2322 - wos: WOS:001018507300012 (7) - scopus: 2-s2.0-85162940767 (10)

11573/1692790 - 2023 - Electrospinning technology to upscale the production of low-cost and high-filtering functionalized polymer-based nanofibers providing photocatalytic activity for bacterial inactivation in advanced face mask
Cimini, Adriano; Borgioni, Alessia; Mancini, Chiara; Proietti, Anacleto; Buccini, Luca; Stornelli, Eleonora; Schifano, Emily; Dinarelli, Simone; Mura, Francesco; Passeri, Daniele; Imperi, Enrico; Rinaldi, Teresa; Picano, Alfredo; Rossi, Marco - 04d Abstract in atti di convegno
congresso: NANOCON 2023 (Brno (Repubblica Ceca))
libro: Nanocon 2023 - ()

11573/1692785 - 2023 - Upscaling of Electrospinning Technology and the Application of Functionalized PVDF-HFP@TiO2 Electrospun Nanofibers for the Rapid Photocatalytic Deactivation of Bacteria on Advanced Face Masks
Cimini, Adriano; Borgioni, Alessia; Passarini, Elena; Mancini, Chiara; Proietti, Anacleto; Buccini, Luca; Stornelli, Eleonora; Schifano, Emily; Dinarelli, Simone; Mura, Francesco; Sergi, Claudia; Bavasso, Irene; Cortese, Barbara; Passeri, Daniele; Imperi, Enrico; Rinaldi, Teresa; Picano, Alfredo; Rossi, Marco - 01a Articolo in rivista
rivista: POLYMERS (Basel : Molecular Diversity Preservation International) pp. - - issn: 2073-4360 - wos: WOS:001117505800001 (5) - scopus: 2-s2.0-85179129565 (6)

11573/1697357 - 2023 - Strain characterization in SiGe epitaxial samples by Tip Enhanced Raman Spectroscopy
La Penna, Giancarlo; Mancini, Chiara; Proietti, Anacleto; Silvestri, Serena; Buccini, Luca; Passeri, Daniele; Gambacorti, Narciso; Richy, Jerome; Rossi, Marco - 04f Poster
congresso: Nanoinnovation 2023 Conference & Exhibition (Faculty of Civil and Industrial Engineering (via Eudossiana) - Sapienza University of Rome, Roma)
libro: Nanoinnovation 2023: book of abstract, poster session - ()

11573/1684898 - 2023 - Strain characterization in SiGe epitaxial samples by Tip Enhanced Raman Spectroscopy
La Penna, Giancarlo; Mancini, Chiara; Proietti, Anacleto; Silvestri, Serena; Buccini, Luca; Passeri, Daniele; Gambacorti, Narciso; Richy, Jérôme; Rossi, Marco - 04f Poster
congresso: VISPEC 2023 School & Conference (Perugia, Italy)
libro: VISPEC 2023: book of abstract, poster session - ()

11573/1689233 - 2023 - Influence of the conductive coating on combined {CPEM} and Raman analysis
Mura, F; Dinarelli, S; Mancini, C; Proietti, A; Buccini, L; Silvestri, S; Passeri, D; Rossi, Marco - 04h Atto di convegno in rivista scientifica o di classe A
rivista: JOURNAL OF PHYSICS. CONFERENCE SERIES (Bristol : Institute of Physics Publishing) pp. 012012- - issn: 1742-6588 - wos: (0) - scopus: 2-s2.0-85173004205 (1)
congresso: Nanoinnovation 2022 (Rome)

11573/1684897 - 2023 - Challenges - real time nano characterization related technlogieeS
Proietti, Anacleto; La Penna, Giancarlo; Mancini, Chiara; Passeri, Daniele; Gambacorti, Narciso; Galiazzo, Marco; Zurutuza, Amaia; Centeno, Alba; Rossi, Marco - 04f Poster
congresso: EuroNanoForum 2023 (Lund; Sweden)
libro: EuroNanoForum 2023: Poster session - ()

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